Dice onion, bell pepper, green onions, and carrots. Add to crockpot and pour in broth; top with pork chops. Cook on low for 5-6 hours until pork is no longer pink.
Approximately one hour before pork has finished cooking, preheat oven to 400ºF. Place oven rack in the center of oven.
Quarter potatoes and slice shallots in half; add both to a large bowl. Toss with olive oil, salt, and pepper. Spread into a large baking dish and cook approximately 40 minutes until potatoes are browned and crisped around the edges.
Serve pork with veggies, potatoes, and apple slices on the side.